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Aromatic compounds, originally named because of their fragrant properties, are unsaturated hydrocarbon ring structures that exhibit special properties, including unusual stability, due to their aromaticity.
They are often represented as resonance structures containing single and double bonds.
However, the bonding is stronger than expected for a conjugated structure, and it is more accurately depicted as delocalized electron density shared between all the atoms in the ring.
Structure of Aromatic Compounds
Aromatic compounds are cyclic structures in which each ring atom is a participant in a pi bond, resulting in delocalized pi electron density on both sides of the ring.
Due to this connected network of pi bonds, the rings are planar, unlike the boat or table structures typical of cycloalkanes.
Aromatic compounds are generally nonpolar and immiscible with water.
As they are often unreactive, they are useful as solvents for other nonpolar compounds.
Due to their high ratio of carbon to hydrogen, aromatic compounds are characterized by a sooty yellow flame.
The double bonds in aromatic compounds are less likely to participate in addition reactions than those found in typical alkenes.
Having pi electrons, aromatic compounds can act as Lewis bases, and they often participate in electrophilic substitution reactions.
Aromatic compounds can also react in nucleophilic aromatic substitution reactions.
Sources of Aromatic Compounds
Aromatic compounds are produced from a variety of sources, including petroleum and coal tar.
Poly-aromatic hydrocarbons are components of atmospheric pollution and are known carcinogens.
Aromatic compounds are also interesting because of their role in the origins of life as precursors to nucleotides and amino acids.
Aromatic compounds often have fragrant properties, Aromatic compounds, unlike their cycloalkane cousins, are flat, Aromatic compounds produce a sooty yellow flame when burned due to their high C:H ratio, and Aromatic compounds are highly reactive due to their delocalized electrons