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Aromatic compounds, originally named because of their fragrant properties, are unsaturated hydrocarbon ring structures that exhibit special properties, including unusual stability, due to their aromaticity. They are often represented as resonance structures containing single and double bonds. However, the bonding is stronger than expected for a conjugated structure, and it is more accurately depicted as delocalized electrondensity shared between all the atoms in the ring.
Aromatic compounds are cyclic structures in which each ring atom is a participant in a$\pi$ bond, resulting in delocalized $\pi$ electron density on both sides of the ring. Due to this connected network of $\pi$ bonds, the rings are planar, unlike the boat or table structures typical of cycloalkanes.
Physical Properties of Aromatic Compounds
Aromatic compounds are generally nonpolar and immiscible with water. As they are often unreactive, they are useful as solvents for other nonpolar compounds. Due to their high ratio of carbon to hydrogen, aromatic compounds are characterized by a sooty yellow flame.
The double bonds in aromatic compounds are less likely to participate in addition reactions than those found in typical alkenes. Instead, cyclic aromatic compounds undergo electrophilic substitution reactions (reactions in which the ring acts as an nucleophile to a suitable electrophile). When benzene participates in such substitution reactions, the product retains the stability associated with the aromatic $\pi$ electron system. This stability is lost in electrophilic addition because the product is not aromatic.
Aromatic compounds are produced from a variety of sources, including petroleum and coal tar. Poly-aromatic hydrocarbons are components of atmospheric pollution and are known carcinogens. Aromatic compounds are also interesting because of their presumed role in the origin of life as precursors to nucleotides and amino acids.